Sustainability

Ban on polluted water from ships' exhaust gases in Danish coastal areas

DTU research contributes to new legislation banning the discharge of polyaromatic hydrocarbons (PAHs) and heavy metals from ships' exhaust gases, known as scrubber water.

The sea will get a helping hand when new Danish legislation comes into force on 1 July 2025, prohibiting the discharge of polluted water from ships' exhaust gases in Danish coastal areas. Photo: Colourbox.

Facts

A scrubber works by removing pollutants from a ship's exhaust gases by passing them through a pipe where they meet a liquid, typically water or a chemical solution. The liquid is sprayed into the pipe in droplets, which meet the pollutants in the gas.

The pollutants are then absorbed or neutralized by the liquid, which converts them into sulphur dioxide (SO₂), that can react with water to form sulphuric acid (H₂SO₄), the sulphuric acid is then removed.

There are three main types of scrubbers.

  • Open systems, which use seawater to clean the exhaust gases. The water is treated and then discharged back into the sea.
  • Closed systems that use fresh water treated with alkaline chemicals. The water is reused several times and treated before being discharged or delivered to facilities on land.
  • Hybrid systems that can function as both open and closed systems and can switch between using seawater and fresh water.

Mapping chemical impact

Professor Marja Kaarina Koski was one of the DTU researchers who, back in 2016, documented how chemicals from scrubber water influenced plankton, which is the base of the marine food chain.

In an ongoing study, DTU researchers are mapping how the cocktail of chemicals in scrubber water affects dominant zooplankton in Danish coastal waters, including organisms such as copepods. According to Marja Kaarina Koski, documenting how local species are affected is crucial.

"If we are to document how scrubber water affects the marine environment, we need to look at cocktail effects. Chemical substances react with each other, and the organisms' response is affected by the mixture of stress factors to which they are exposed. The strength of our research therefore lies in mapping the mechanisms of organisms' responses to cumulative effects that can be transferred to other areas, and in documenting specific effects on organisms that live in Danish waters," Marja Kaarina Koski says.

Air pollution from ships became pollution of the sea

The use of scrubbers gained momentum around 2015 when the International Maritime Organization (IMO) set stricter rules on how much sulphur ships were allowed to emit and introduced emission controls in areas such as the North Sea and the Baltic Sea. The IMO rules required that the sulphur content of marine fuel must not exceed 0.1% in these areas. In 2020, global rules became even stricter with new IMO requirements for a maximum sulphur content of 0.5% in marine fuel worldwide.

The sulphur content in ship fuel is not reduced by combustion, but is emitted in the smoke from the ship, primarily in the form of sulphur dioxide. Scrubbers are therefore a way of meeting the requirements without using the more expensive low sulphur fuel, because they wash the sulphur out of the exhaust gases and bind it in a liquid (e.g., sea water) that can be discharged into the sea. However, as a result of this process, the liquid also contains several heavy metals such as vanadium and nickel, and PAH substances such as naphthalene and phenanthrene.

Ban out to 22 kilometers

The ban on the discharge of scrubber water applies in the sea within 22 kilometers of the coast. The sea area beyond 22 kilometers is regulated by international rules, and the political parties behind the ban therefore agree that Denmark should work for a similar ban in the EU.

Under the new legislation, ships will in future have to switch to either low-sulphur fuel or closed scrubbers with zero discharge. This means that the residual product from the closed scrubber must be delivered to the ports' reception facilities. The ban will come into force on 1 July 2025 for ships with open loop scrubbers. For ships with closed scrubbers, the ban will come into force on 1 July 2029.

The research on scrubber water has been conducted by DTU's maritime centre, Maritime DTU, in collaboration with industry and authorities and with support from The Danish Maritime Fund and A/S D/S Orient's Fund.

Facts

In 2020, the independent, non-profit research organization International Council on Clean Transportation estimated that 68 million tons of scrubber water is discharged within 22 km of the coast in Denmark. This makes Denmark the country in the world with the sixth largest amount discharged to date.

A new analysis of the total human pressure on Danish marine areas, prepared by the Danish branch of the Norwegian Institute for Water Research, NIVA Denmark, shows that environmentally hazardous substances are the third largest pressure factor on the marine environment.

Ireland, Germany, Norway, Spain and Portugal have introduced bans on the discharge of scrubber water in ports, fjords and/or inland waterways, while France and Belgium have bans extending 5.5 km from the coast, and Latvia has a ban extending 22 km. Internationally, the discharge of open-loop scrubbers is banned in more than 120 ports worldwide.

In Denmark, the ban means that it is no longer permitted to discharge scrubber water into the Baltic Sea, the Kattegat and the Skagerrak.